Removal of Astrazon yellow dye from aqueous solutions by sorption onto Stipa tenacissima L Alfa fibers as a natural adsorbent
Abstract
Abstract: This work aims to explore the use of alfa fibers as a natural and low-cost adsorbent for the removal of astrazon yellow dye (AY) from aqueous solution on industrial textile effluent. The alkaline procedure was used to remove none cellulosic substances such as pectin, lignin and hemicellulose. The influence of alkaline treatment on fiber morphology is analyzed by FT-IR and SEM, showing physico-chemical changes in the treated material. The observations show that an interesting mesoporous structure was developed. The specific surface was notably increased to 62.48 m2/g. Batch adsorption experiments, at 25 C° and agitation speed of 150 rpm, were carried out and the effects of operational parameters including contact time, initial dye concentration, adsorbent dose, and pH solution on adsorbed amount were investigated and discussed.
Batch adsorption shows that equilibrium was obtained after 40 min, and the adsorbed dye amount increases with pH. The highest removal rate was about 83 %. The experimental data of modelization showed that data were best fitted with the Freundlich model. The correlation coefficient values (R2) showed that the adsorptions Kinetic were well described by the pseudo-second-order model. The adsorption thermodynamics and isotherms are consistent with spontaneous endothermic physicosorption. The results indicated that alfa fibers could be used effectively and advantageously to adsorb astrazon yellow dye from aqueous solutions.Full Text:
PDFReferences
Santhi, T.; Manonmani, S.; Vasantha, V.S.; Chang, Y.T. A new alternative adsorbent for the removal of cationic dyes from aqueous solution. Arabian Journal of Chemistry 9 (2016) S466-S474.
Ebrahimian Pirbazari, A.; Saberikhah, E. ; Badrouh, M.; Emami, M.S. Alkali treated Foumanat tea waste as an efficient adsorbent for methylene blue adsorption from aqueous solution. Water Resources and Industry 6 (2014) 64-80.
Auta, M.; Hameed, B.H. Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. Chemical Engineering Journal 198-199 (2012) 219-227.
Bulut, Y.; Aydın, H. A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination 194 (2006) 259-267.
Arami, M.; Limaee, N.Y.; Mahmoodi, N.M.; Tabrizi, N.S. Removal of dyes from colored textile wastewater by orange peel adsorbent: equilibrium and kinetic studies. Journal Colloid Interface Science 288 (2005) 371-376.
Zhao, B.; Xiao, W.; Shang, Y.; Zhu, H. ; Han, R. Adsorption of light green anionic dye using cationic surfactant-modified peanut husk in batch mode. Arabian Journal of Chemistry 10 (2017) S3595-S3602.
Moussavi, G.; Khosravi, R. The removal of cationic dyes from aqueous solutions by adsorption onto pistachio hull waste. Chemical Engineering Research and Design 89 (2011) 2182-2189.
Rasheed Khan, A.; Tahir, H. ; Uddin, f. ; Hameed, U. Adsorption of Methylene Blue from aqueous Solution on the Surface of Wool Fiber and Cotton Fiber. Journal Applied Science. Environment 9(2) (2005) 29-35.
Demirbas, E.; Kobya, M. ; Sulak, M.T. Adsorption kinetics of a basic dye from aqueous solutions onto apricot stone activated carbon. Bioresource Technology 99 (2008) 5368-5373.
Sulak, M.T.; Demirbas, E. ; Kobya, M. Removal of Astrazon Yellow 7GL from aqueous solutions by adsorption onto wheat bran. Bioresource Technology 98 (2007) 2590-2598.
Tekbaş, M.; Bektaş, N.; Yatmaz, H.C. Adsorption studies of aqueous basic dye solutions using sepiolite. Desalination 249 (2009) 205-211.
Trache, D.; Donnot, A.; Khimeche, K.; Benelmir, R. ; Brosse, N. Physico-chemical properties and thermal stability of microcrystalline cellulose isolated from Alfa fibres. Carbohydrate Polymers 104 (2014) 223-230.
El Ghali, A.; Baouab, M.H.V.; Roudesli, M.S. Stipa tenacessima L cationized fibers as adsorbent of anionic dyes. Journal of Applied Polymer Science (2010) NA-NA.
Meghchiche, A.; Haouam, A.; Immirzi, B. Extraction and Characterization of Algerien Alfa Grass Short Fibers (Stipa Tenacissima). Chemestry & Chemestry Technology (2013) 339-344.
Faruk, O.; Bledzki, A.K.; Fink, H.-P.; Sain, M. Biocomposites reinforced with natural fibers: 2000–2010. Progress in Polymer Science 37 (2012) 1552-1596.
Belaid, K.D.; Kacha, S. Étude cinétique et thermodynamique de l’adsorption d’un colorant basique sur la sciure de bois. Revue des sciences de l'eau 24 (2011) 131.
Benyahia, A.; Merrouche, A.; Rahmouni, Z.E.A. ; Rokbi, M. ; Serge, W. ; Kouadri, Z. Study of the alkali treatment effect on the mechanical behavior of the composite unsaturated polyester-Alfa fibers. Mechanics & Industry 15 (2014) 69-73.
Bessadok, A.; Marais, S.; Gouanve, F.; Colasse, L.; Zimmerlin, I.; Roudesli, S.; Métayer, M. Effect of chemical treatments of Alfa (Stipa tenacissima) fibres on water-sorption properties. Composites Science and Technology 67 (2007) 685–697.
Bessadok, A.; Langevin, D.; Gouanvé, F.; Chappey, C. ; Roudesli, S. ; Marais, S. Study of water sorption on modified Agave fibres. Carbohydrate Polymers 76 (2009) 74-85.
Boumehdi Toumi, L.; Hamdi, L. Salem, Z. ; Allia, K. Batch adsorption of methylene blue from aqueous solutions by untreated Alfa grass. Desalination and Water Treatment 53 (2013) 806-817.
Ismail, L.F.M.; Sallam, H.B.; Abo Farha, S.A. ; Gamal, A.M.; Mahmoud, G.E.A. Adsorption behaviour of direct yellow 50 onto cotton fiber: equilibrium, kinetic and thermodynamic profile. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 131 (2014) 657-666.
Etim, U.J.; Umoren, S.A.; Eduok, U.M. Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution. Journal of Saudi Chemical Society 20 (2016) S67-S76.
Bazrafshan, E.; Mostafapour, F.-K.; Zazouli, M.-A. Methylene blue (cationic dye) adsorption into Salvadora persica stems ash. African Journal of Biotechnology 11(101) (2012) 16661-16668,.
Yeddou, N.; Bensmaili, A. Equilibrium and kinetic modelling of methylene blue biosorption by pretreated dead streptomyces rimosus: Effect of temperature. Chemical Engineering Journal 119 (2006) 121-125.
Salleh, M.A.M.; Mahmoud, D.K.; Karim, W.A.W.A. ; Idris, A. Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination 280 (2011) 1-13.
Baghdadi, M.; Mazarji, M.; Sabouhi, M.; Jafari-Kang, A. ; Jafari, A. Removal of cationic surfactants from aqueous solutions by modified cotton as novel high capacity and lowcost adsorbant. Journal of dvances in Chemistry (2014) 2061-2071.
Senthil Kumar, P.; Abhinaya, R.V.; Gayathri Lashmi, K.; Arthi, V.; Pavithra, R.; Sathyaselvabala, V.; Dinesh Kirupha, S.; Sivanesan, S. Adsorption of methylene blue dye from aqueous solution by agricultural waste: Equilibrium, thermodynamics, kinetics, mechanism and process design. Colloid Journal 73 (2011) 651-661.
Ho, Y.S.; McKay, G. Sorption of dye from aqueous solution by peat. Chemical Engineering Journal 70 (1998) 115-124.
Çakmak, M.; Taşar, Ş.; Selen, V.; Özer, D.; Özer, A. Removal of astrazon golden yellow 7GL from colored wastewater using chemically modified clay. Journal of Central South University 24 (2017) 743-753.
Yener, J.; Kopac, T.; Dogu, G.; Dogu, T. Adsorption of Basic Yellow 28 from aqueous solutions with clinoptilolite and amberlite. Journal Colloid Interface Science 294 (2006) 255-264.
Çalışkan, Y.; Harbeck, S.; Bektaş, N. Adsorptive Removal of Basic Yellow Dye Using Bigadiç Zeolites: FTIR Analysis, Kinetics, and Isotherms Modeling. Environmental Progress & Sustainable Energy 38 (2019) S185-S195.
Bulut, Y.; Gozubenli, N.; Aydin, H. Equilibrium and kinetics studies for adsorption of direct blue 71 from aqueous solution by wheat shells. Journal Hazardous Materials 144 (2007) 300-306.
Demir, H.; Top, A.; Balkose, D.; Ulku, S. Dye adsorption behavior of Luffa cylindrica fibers. Journal Hazardous Materials 153 (2008) 389-394.
Crini, G. Kinetic and equilibrium studies on the removal of cationic dyes from aqueous solution by adsorption onto a cyclodextrin polymer. Dyes and Pigments 77 (2008) 415-426.
Yang, T.; Wang, L. Adsorptive Removal of Methylene Blue from Aqueous Solution by Spent Mushroom Substrate: Equilibrium, Kinetics, and Thermodynamics. BioResources 8(3) (2013) 4722-4734.
Refbacks
- There are currently no refbacks.